Exposure Limits
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The NIOSH recommended exposure limits (RELs) are listed first in this column. Unless noted otherwise, RELs are time-weighted average (TWA) concentrations for up to a 10-hour workday during a 40-hour workweek. A short-term exposure limit (STEL) is designated by "ST" preceding the value; unless noted otherwise, the STEL is a 15-minute TWA exposure that should not be exceeded at any time during a workday. A ceiling REL is designated by "C" preceding the value; unless noted otherwise, the ceiling value should not be exceeded at any time. Any substance that NIOSH considers to be a potential occupational carcinogen is designated by the notation "Ca" see (Appendix A, which contains a brief discussion of potential occupational carcinogens).

The OSHA permissible exposure limits (PELs), as found in Tables Z-1, Z-2, and Z-3 of the OSHA General Industry Air Contaminants Standard (29 CFR 1910.1000), that were effective on July 1, 1993* and which are currently enforced by OSHA are listed next. [*Note: In July 1992, the 11th Circuit Court of Appeals in its decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992) vacated more protective PELs set by OSHA in 1989 for 212 substances, moving them back to PELs established in 1971. The appeals court also vacated new PELs for 164 substances that were not previously regulated. The substances for which OSHA PELs were vacated on June 30, 1993 are indicated by the symbol "†" following OSHA PEL in this column. A number of RELs are based on NIOSH concurrence with the data presented and the airborne exposure limits proposed in this rulemaking.] Unless noted otherwise, PELs are TWA concentrations that must not be exceeded during any 8-hour workshift of a 40-hour workweek. A STEL is designated by "ST" preceding the value and is measured over a 15-minute period unless noted otherwise. OSHA ceiling concentrations (designated by "C" preceding the value) must not be exceeded during any part of the workday; if instantaneous monitoring is not feasible, the ceiling must be assessed as a 15-minute TWA exposure. In addition, there are a number of substances from Table Z-2 (e.g., beryllium, ethylene dibromide, etc.) that have PEL ceiling values that must not be exceeded except for specified excursions. For example, a "5-minute maximum peak in any 2 hours" means that a 5-minute exposure above the ceiling value, but never above the maximum peak, is allowed in any 2 hours during an 8-hour workday. Appendix B contains a brief discussion of substances regulated as carcinogens by OSHA.

Concentrations are given in ppm, mg/m3, mppcf (millions of particles per cubic foot of air as determined from counting an impinger sample), or fibers/cm3 (fibers per cubic centimeter). The "[skin]" designation indicates the potential for dermal absorption; skin exposure should be prevented as necessary through the use of good work practices and gloves, coveralls, goggles, and other appropriate equipment. The "(total)" designation indicates that the REL or PEL listed is for "total particulate" versus the "(resp)" designation which refers to the "respirable fraction" of the airborne particulate. Appendix C contains more detailed discussions of the specific exposure limits for certain low-molecular-weight aldehydes, asbestos, various dyes (benzidine-, o-tolidine-, and o-dianisidine-based), carbon black, the various chromium compounds (chromic acid and chromates, chromium(II) and chromium(III) compounds, and chromium metal), coal tar pitch volatiles, coke oven emissions, cotton dust, lead, NIAX Catalyst ESN, trichloroethylene, and tungsten carbide (cemented). Appendix D contains a brief discussion of substances included in the Pocket Guide with no established RELs at this time and Appendix F contains miscellaneous notes regarding the OSHA PELs. Appendix G lists the OSHA PELs that were vacated on June 30, 1993.]

 

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